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2020 Vol.29, Issue 5 Preview Page

Research Paper

Solvent Extraction Separation of Co(II) and Ni(II) from Weak Hydrochloric Acid Solution with Ionic Liquids Synthesized from Organophosphorus Acids

유기인산계 추출제로 합성한 이온성액체에 의한 묽은 염산용액에서 코발트(II)와 니켈(II)의 추출분리

Hyun Seung Moon1
,
Si Jeong Song1
,
Thanh Tuan Tran1*
,
Man Seung Lee1
문 현승1
,
송 시정1
,
Tran Thanh Tuan1*
,
이 만승1
1Department of Advanced Material Science & Engineering, Institute of Rare metal, Mokpo National University
1목포대학교 공과대학 신소재공학과
*Corresponding Author
31 October 2020. pp. 55-63
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Abstract

In order to investigate the separation of Co(II) and Ni(II) by ionic liquids from weak hydrochloric acid solutions, extraction experiments were performed by changing the type and concentration of ionic liquids and the initial pH of the aqueous phase. Two kinds of ionic liquids based on Aliquat 336 were employed in this work; one was synthesized by reacting organophosphorus acids(D2EHPA, PC88A, Cyanex 272, Cyanex 301) with Aliquat 336 and the other was prepared by exchanging the chloride ion of Aliquat 336 with SCN-. The three types of ionic liquids (ALi-D2, ALi-PC, and ALi-CY272) showed better extraction of Co(II) than Ni(II), and the equilibrium pH was higher than the initial pH. In the case of ALi-CY301, the selectivity of Co(II) and Ni(II) depended on the extraction conditions. In addition, the effect of the addition of TBP to the ionic liquid on the extraction of two metals was also investigated. Employment of ALi-SCN as an extractant resulted in selective extraction of Co(II) and complete separation of the two metal ions was possible.

Keywords
Cobalt(II)
Nickel(II)
solvent extraction
ionic liquids

묽은 염산용액에서 이온성액체에 의한 코발트(II)와 니켈(II)의 분리를 조사하기 위해 이온성액체의 종류와 농도 및 수상의 초기 pH를 변화시켜 추출실험을 수행했다. 본 논문에서는 유기인산(D2EHPA, PC88A, Cyanex 272, Cyanex 301)을 Aliquat 336과 반응시켜 제조한 이온성액체와 Aliquat 336의 염소이온을 SCN-과 치환한 이온성액체를 사용했다. 세 종류의 이온성액체(ALi-D2, ALi-PC, ALi- CY272)에 코발트(II)가 니켈(II)보다 추출이 잘 되었으며 평형 pH가 초기 pH보다 높았다. ALi-CY301의 경우 코발트(II)와 니켈(II)의 선택도는 추출조건에 의존했다. 또한 상기 이온성액체에 TBP의 첨가가 두 금속의 추출에 미치는 영향도 조사했다. 추출제로 ALi-SCN를 사용하는 조건에서 코발트(II)가 선택적으로 추출되어 두 금속을 완전히 분리하는 것이 가능했다.

키워드
코발트(II)
니켈(II)
용매추출
이온성액체
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Information
  • Publisher :The Korean Institute of Resources Recycling
  • Publisher(Ko) :한국자원리싸이클링학회
  • Journal Title :Journal of the Korean Institute of Resources Recycling
  • Journal Title(Ko) :자원리싸이클링
  • Volume : 29
  • No :5
  • Pages :55-63
  • Received Date : 2020-09-15
  • Revised Date : 2020-09-28
  • Accepted Date : 2020-10-06
  • DOI :https://doi.org/10.7844/kirr.2020.29.5.55
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