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2021 Vol.30, Issue 3 Preview Page

Article Review

Smelting of Platinum Group Metals and Recycling of Spent Catalyst

백금족 금속의 제련과 폐촉매의 리사이클링

Injoon Son1
,
Ho-Sang Sohn1*
손 인준1
,
손 호상1*
1School of Materials Science and Engineering, Kyungpook National University, Daegu 41566, Korea
1경북대학교 신소재공학부
*Corresponding Author
30 June 2021. pp. 18-29
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Abstract

Platinum group metals (PGMs) are used in a wide range of application fields such as catalysts, electronic devices, electrodes, electrical devices, fuel cells and high temperature materials due to their excellent electrical and thermal conductivity as well as chemical resistivity. Platinum group elements are generally associated with nickel-copper sulfides in magmatic rocks. Depending on the relative concentrations of the PGMs, they are produced either as the primary products or as by-products of the nickel and copper. However, PGMs natural resource deposits are strictly limited in countries such as South Africa and Russia. The annual supply of PGMs is only under 500 t. Considering the limited supply of PGMs, there will be a noticeable increase in the supply risk associated with PGMs in the near future. Therefore, it is extremely important to recover PGMs from secondary resources such as spent catalysts. This paper reviews on overview of PGMs extraction and recycling processes.

Keywords
Platinum group metals (PGMs)
extration
recycling
resource
catalyst

백금족 금속(Platinum Group Metals, PGMs)은 화학적 저항성은 물론 전기·열전도성이 뛰어나 촉매, 전자기기, 전극, 전기기기, 연료전지, 고온 소재 등 광범위한 응용 분야에 사용된다. 일반적으로 백금족 금속은 구리와 니켈의 황화광과 관련되어 있으므로 백금족 금속의 상대적인 농도에 따라 주산물로 생산되거나 니켈과 구리의 부산물로 생산된다. 특히 이러한 자원들은 남아프리카와 러시아 같은 나라들에 편재되어 있으며, 백금족 금속의 연간 공급량은 500톤 미만이다. 이와 같은 백금족 금속의 한정된 공급량을 고려하면 향후에 백금족 금속의 공급 리스크가 증가할 것이다. 따라서 폐촉매와 같은 2차 자원으로부터 백금족 금속을 회수하는 것이 매우 중요하다. 본 논문에서는 백금족 금속의 제련 기술과 리사이클링 기술에 대하여 고찰하였다.

키워드
백금족 금속
제련
리사이클링
자원
촉매
References
1
Habashi, F., 2003 : Two hundred years platinum group metals, Metall, 57, pp.732-739.
2
Hammond, C. R., 2014 : Sec. 4 Properties of the Elements and Inorganic Compounds, CRC Handbook of Chemistry and Physics 95th Ed. (2014-2015), pp.4.44-4.101, Ed. by Haynes, W. M., CRC Press.
3
Jones, R.T., 2005 : An overview of Southern African PGM smelting, Procd. of Nickel and Cobalt 2005: Challenges in Extraction and Production, 44th Annual Conference of Metallurgists, pp.147-178, 21-24 August 2005, Calgary, Alberta, Canada.
4
Lee, Man-Seung and Lee, Jin-Young, 2009 : Ionic Equilibria of Pt(IV), Pd(II) and Rh(III) in Hydrochloric Acid Solution, J. of Korean Inst. of Resources Recycling, 18(1), pp.30-37.
5
Yamabe-Mitarai, Y., Zebin, B., Murakami, H., et al., 2011 : Effective Use of Platinum Group Metals, J. Japan Inst. Metals, 75(1), pp.10-20. 10.2320/jinstmet.75.10
6
The International Platinum Group Metals Association, Ch. 3 Production and Uses of Platinum Group Metals, p.9. IPA.
7
Christian Hagelüken, 2012 : Recycling the Platinum Group Metals: A European Perspective, Platinum Metals Rev., 56(1), pp.29-35. 10.1595/147106712X611733
8
U.S. Geological Survey, 2014, Platinum-group metals statistics, in Kelly, T.D., and Matos, G.R., comps., Historical statistics for mineral and material commodities in the United States: U.S. Geological Survey Data Series, 140, accessed 2019, at http://minerals.usgs.gov/minerals/pubs/ historical-statistics/
9
Philip Klapwijk, Paul Walker, Peter Ryan, et al., 2010 : Platinum & Palladium Survey 2010, pp.21-26, GFMS Limited, London, UK.
10
Rhona O’Connell, Cameron Alexander, Ross Strachan, et al., 2017 : GFMS Platinum Group Metals Survey 2017, pp.18-22, GFMS Limited, London, UK.
11
Cameron Alexander, Saida Litosh, Bruce Alway, et al., 2019 : GFMS Platinum Group Metals Survey 2019, pp. 18-21, GFMS Limited, London, UK.
12
Okabe, T. H., 2007 : Current Status of Platinum Group Metals and Recycling Technologies, Materia Japan, 46(8), pp.522-529. 10.2320/materia.46.522
13
International Platinum Group Metals Association, The Primary Production of Platinum Group Metals (PGMs), www.ipa-news.com
14
Sohn, Hosang, 2019 : Engineering of Resources Recycling, p.303, KNU Press, Daegu, Korea.
15
Okabe, T. H., Nakada, H., and Morita, K., 2008 : Recovery Technology of Platinum Group Metals, Journal of The Surface Sicence Society of Japan, 29(10), pp.592-600. 10.1380/jsssj.29.592
16
Okabe, T. H., Yamamoto, S., Kayanuma, Y., et al., 2003 : Recovery of Platinum Using Magnesium Vapor, J. Mater. Res., 18, pp.1960-1967. 10.1557/JMR.2003.0272
17
Okabe, T. H., Kayanuma, Y., Yamamoto, S., et al., 2003: Platinum Recovery Using Calcium Vapor Treatment, Mat. Trans. JIM, 44, pp.1386-1393. 10.2320/matertrans.44.1386
18
Kayanuma, Y., Okabe, T. H., Mitsuda, Y., et al., 2004 : New Recovery Process for Rhodium Using Metal Vapor, J. Alloy. Compd., 365, pp.211-220. 10.1016/S0925-8388(03)00666-2
19
Taninouchi, Y., and Okabe, T. H., 2018 : Recovery of Platinum Group Metals from Spent Catalysts Using Iron Chloride Vapor Treatment, Metall. & Mater. Trans. B, 49B, pp.1781-1793. 10.1007/s11663-018-1269-9
20
Lee, Manseung, 2010 : Chemical Properties and Dissolution Technology of Platinum Group Metals in Solutions, J. of Korean Inst. of Resources Recycling, 19(5), pp.3-12.
21
Tanaka, M., 2007 : Gold and Silver Smelting at Mitsui Kushikino Mining Co., Ltd., J. MMIJ, 123(12), pp.675-677. 10.2473/journalofmmij.123.675
22
Shibata, J., and Okuda, A., 2002 : Recycling Technology of Precious Metals, Shigen-to-Sozai, 118(1), pp.1-8. 10.2473/shigentosozai.118.1
23
Nguyen, T. H. and Lee, M. S., 2017 : Solvent Extraction for the Separation of Pd(II), Pt(IV), Ir(IV) and Rh(III) from 3 M Hydrochloric Acid Solution, J. of Korean Inst. of Resources Recycling, 26(3), pp.26-31.
24
Frank K. Crundwell, Michael S. Moats, Venkoba Ramachandran Timothy G. Robinson, et al., 2011 : Ch. 37 Refining of the Platinum-Group Metals, Extractive Metallurgy of Nickel, Cobalt and Platinum-Group Metals, p.513, 517, Elsevier, Amsterdam, Netherlands. 10.1016/B978-0-08-096809-4.10037-1
25
Narita, H., Suzuki, T., and Motokawa, R., 2017 : Recent Research in Solvent Extraction of Platinum Group Metals, JIM, 81(4), pp.157-167. 10.2320/jinstmet.JE201604
26
Lee, J. C., Jeong, J. K., Kim, M. S, et al., 2004 : Recovery of Platinum Group Metals from Spent Automotive Catalysts by Hydrochloric Acid Leaching, J. of Korean Inst. of Resources Recycling, 13(5), pp.28-36.
27
Lee, J. C., Jeong, J., Kim, B. S., et al., 2004 : Sulfuric Acid Dissolution of Carriers for Recovering Platinum from the Spent Petroleum Catalysts, J. of Korean Inst. of Resources Recycling, 13(1), pp.14-21.
28
Harjanto, S., Cao, Y., Shibayama, A., et al., 2006 : Leaching of Pt, Pd and Rh from Automotive Catalyst Residue in Various Chloride Based Solutions, Materials Trans., 47(1), pp.129-135. 10.2320/matertrans.47.129
29
Nakamura, S., Kojima, N., and Yokoyama, K., 2007 : Current Status of Recycling PGMs from Scrapped Autocatalysts, MMIJ, 123(12), pp.799-802. 10.2473/journalofmmij.123.799
30
Kim, W. T., Kim, H. S., Cho, S. B., et al., 2008 : Effect of Attrition Scrubbing on the Recovery of Platinum Group Metals from Spent Automobile Catalytic Converters, J. of Korean Inst. of Resources Recycling, 17(5), pp.28-36.
31
Sun, P. P. and Lee, M. S., 2013 : Recovery of Pt from the Chloride Leaching Solution of Spent Catalysts by using Column Extractor, J. of Korean Inst. of Resources Recycling, 22(6), pp.26-32. 10.7844/kirr.2013.22.6.26
32
Fujima, K., Morimoto, T., Itoigawa, H., et al., 2017 : Development of a Process for Recycling Platinum Group Metals Using Molten Alkali Metal Chlorides, J. Japan Inst. Met. Mater., 81(4), pp.168-177. 10.2320/jinstmet.JE201602
33
Frank K. Crundwell, Michael S. Moats, Venkoba Ramachandran Timothy G. Robinson, et al., 2011 : Ch. 38 Recycling of Nickel, Cobalt and Platinum-Group Metals, Extractive Metallurgy of Nickel, Cobalt and Platinum-Group Metals, p. 542, Elsevier, Amsterdam, Netherlands. 10.1016/B978-0-08-096809-4.10038-3
34
Okabe, T. H., and Nose, K., 2011 : Pyrometallurgical Recycling Processes for Rare Metals and Platinum Group Metals, Journal of Material Cycles and Waste Management, 22(1), pp.50-57. 10.3985/mcwmr.22.50
35
Lee, J. C., Kim, M. S., Yoo, K, et al., 2008 : Extractive Metallurgy of Platinum Group Metals, Trend in Metals & Materials Engineering, 21(6), pp.23-32.
Information
  • Publisher :The Korean Institute of Resources Recycling
  • Publisher(Ko) :한국자원리싸이클링학회
  • Journal Title :Resources Recycling
  • Journal Title(Ko) :자원리싸이클링
  • Volume : 30
  • No :3
  • Pages :18-29
  • Received Date : 2021-02-22
  • Revised Date : 2021-04-09
  • Accepted Date : 2021-04-21
  • DOI :https://doi.org/10.7844/kirr.2021.30.3.18
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