Trend and Future Strategy of Ammonia Gas Recovery based on Adsorption from Livestock Fields

Sangyeop Chae; Kwangmin Ryu; Sang-hun Lee

doi:10.7844/kirr.2023.32.6.45

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2023 Vol.32, Issue 6 Preview Page Next Page

Research Paper

Trend and Future Strategy of Ammonia Gas Recovery based on Adsorption from Livestock Fields 축산현장에서 발생된 암모니아 기체의 흡착기반 회수 동향 및 향후 전략

31 December 2023. pp. 45-53

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Abstract

This study discussed the trend and future strategy of adsorption technology R&D to effectively recover ammonia emitted from the livestock fields. A proper ammonia adsorbent should incorporate acidic or hydrogen bonding functional groups on the surface, as well as a high specific surface area and a good surface structure appropriate for ammonia adsorption. Activated carbon and minerals such as zeolite have widely been used as ammonia adsorbents, but their adsorption effects are generally low, so any improvement through surface modification should be necessary. For example, incorporation of metal chloride included in a porous adsorbent can promote ammonia adsorption effectiveness. Recently, new types of adsorbents such as MOFs (Metal-Organic Frameworks) and POPs (Porous Organic Polymers) have been developed and utilized. They have shown very high ammonia adsorption capacity because of adjustable and high specific surface area and porosity. In addition, Prussian Blue exhibited high ammonia adsorption and desorption performance and selectivity. This looks relatively advantageous in relation to the recovery of ammonia from livestock waste discharge. In the future, further research should be made to evaluate ammonia adsorption/desorption efficiency and purity using various adsorbents under conditions suitable for livestock sites. Also, effective pre- and/or post-treatment processes should be integrated to maximize ammonia recovery.

Keywords

Waste

Ammonia

recovery

adsorption

desorption

livestock

본 연구에서는 축산 분야에서 배출되는 암모니아를 효과적으로 회수할 수 있는 흡착기술의 연구개발 동향 및 향후 전략에 대해 논의하였다. 적절한 암모니아 흡착제는 표면의 산성기나 수소결합기를 가지며 높은 비표면적과 암모니아 흡착에 적절한 표면구조를 지니어야 한다. 일반적인 암모니아 흡착제로는 활성탄이나 제올라이트 등의 광물질이 널리 쓰이나 대체로 흡착효과가 낮아 표면 개질 등을 통한 개선이 필요하다. 일례로 금속염화물이 다공성 흡착제에 포함되었을 때, 활성탄이나 제올라이트의 표면에 흡착 시보다 암모니아 흡착량이 더 증가하는 것으로 알려져 있다. 최근에는 MOFs (Metal-Organic Frameworks)나 POPs (Porous Organic Polymers) 같은 새로운 종류의 흡착제가 개발 및 적용되고 있으며 조절가능한 높은 비표면적과 다공성으로 매우 높은 암모니아 흡착용량을 보였다. 그 외에 프러시안 블루가 높은 암모니아 흡탈착성능 및 선택성을 보였는데. 이는 축산폐기물 배출 암모니아 회수에 관련하여 상대적으로 유리한 측면으로 보인다. 향후 다양한 흡착제를 이용, 축산현장에 맞는 조건에서 암모니아 흡탈착 효율 및 순도를 평가하는 연구가 더 활발히 진행되어야 할 것이다. 아울러 암모니아 회수를 극대화하기 위한 효과적인 전/후처리 공정도 병행되어야 한다.

키워드

폐기물

암모니아

회수

흡착

탈착

축산

References

Lee, S-H., Bae, S., 2022 : A strategy for ammonia odor monitoring, prediction, and reduction from livestock manure wastes in Korea, Geosystem Engineering, 25(1-2), pp.35-43. 10.1080/12269328.2022.2120094

KEI (Korea Environmental Institute), 2017 : Management Strategies to Reduce PM-2.5 Emission: Emphasis-Ammonia, KEI Fundamental Research Report (Korean), pp.1-89.

Jafari, M. J., Matin, A. H., Rahmati, A., et al., 2018 : Experimental optimization of a spray tower for ammonia removal. Atmospheric Pollution Research, 9, pp.783-790. 10.1016/j.apr.2018.01.014

Takahashi, A., Minami, K., Noda, K., et al., 2020 : Trace Ammonia Removal from Air by Selective Adsorbents Reusable with Water, ACS Appl. Mater. Interfaces, 12(13), pp.15115-15119. 10.1021/acsami.9b2238432124600

DeCoste, J. B., Denny, M. S., Peterson, G. W., et al., 2016 : Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption, Chem. Sci., 7(4), pp.2711-2716. 10.1039/C5SC04368A28660045PMC5477018

Han, B., Butterly, C., Zhang, W., et al., 2021 : Adsorbent materials for ammonium and ammonia removal: A review, J. Clean. Prod., 283, 124611. 10.1016/j.jclepro.2020.124611

Khabzina, Y., Farrusseng, D., 2018 : Unravelling ammonia adsorption mechanisms of adsorbents in humid conditions, Microporous Mesoporous Mater, 265, pp.143-148. 10.1016/j.micromeso.2018.02.011

Hao, J. N., Yan, B., 2016 : Simultaneous determination of indoor ammonia pollution and its biological metabolite in the human body with a recyclable nanocrystalline lanthanide functionalized MOF, Nanoscale, 8(5), pp.2881-2886. 10.1039/C5NR06066D26762851

Maia, G. D. N., Day, G. B., Gates, R. S., et al., 2012 : Ammonia biofiltration and nitrous oxide generation during the start-up of gas-phase compost biofilters, Atmos. Environ., 46, pp.659-664. 10.1016/j.atmosenv.2011.10.019

Chen, D. L., Sun, J. L., Bai, M., et al., 2015 : A new cost-effective method to mitigate ammonia loss from intensive cattle feedlots: Application of lignite, Sci. Rep., 5(1), 16689. 10.1038/srep1668926584639PMC4653648

Dong, Y., Yuan, H., Zhang, R., et al., 2019 : Removal of ammonia nitrogen from wastewater: A review, Trans. ASABE, 62(6), pp.1767-1778. 10.13031/trans.13671

Gupta, V. K., Sadegh, H., Yari, M., et al., 2015 : Removal of ammonium ions from wastewater a short review in development of efficient methods, Glob. J. Environ. Sci. Manag., 1(2), pp.149-158.

Kinidi, L., Tan, I. A. W., Wahab, N. B. A., et al., 2018 : Recent development in ammonia stripping process for industrial wastewater treatment, Int. J. Chem. Eng., pp.14. 10.1155/2018/3181087

Ma, Z., Jia, Q., Tao, C., et al., 2020 : Highlighting unique function of immobilized superoxide on TiO₂ for selective photocatalytic degradation, Sep. Purif. Technol., 238, 116402. 10.1016/j.seppur.2019.116402

Rada-Ariza, A. M., Lopez-Vazquez, C. M., van der Steen, N. P., et al., 2017 : Nitrification by microalgal-bacterial consortia for ammonium removal in flat panel sequencing batch photo-bioreactors, Bioresour. Technol., 245, pp.81-89. 10.1016/j.biortech.2017.08.01928892709

Tao, C., Jia, Q. P., Han, B., et al., 2020 : Tunable selectivity of radical generation over TiO₂ for photocatalysis, Chem. Eng. Sci. 214, p.7. 10.1016/j.ces.2019.115438

Ye, Y. Y., Ngo, H. H., Guo, W. S., et al., 2018 : A critical review on ammonium recovery from wastewater for sustainable wastewater management, Bioresour. Technol., 268, pp.749-758. 10.1016/j.biortech.2018.07.11130076073

Zhang, J., Zheng, L., Ma, Y., et al., 2022 : A mini-review on NH3 separation technologies: recent advances and future directions, Energy Fuels, 36(24), pp.14516-14533. 10.1021/acs.energyfuels.2c02511

Pandey, B. and Chen, L., 2021 : Technologies to recover nitrogen from livestock manure - A review, Sci. Total Environ., 784, 147098. 10.1016/j.scitotenv.2021.14709833901956

Kim, S.-D., Kwak, J.-H., Min, K.-M., et al., 2017 : System development of ammonia deaeration and adsorption/desorption, Final report of Project(2014000150007), Korea Environmental Industry & Technology Instituter, Seoul, Korea.

Lee, M.-K., Kim, D., Kim, K., et al., 2019 : Policy improvement to reduce odor and environmental pollution in agricultural and livestock industry, KREI basic research report R896 Research document 1, pp.1-177, Korea Rural Economic Institute, Naju, Korea.

Kim, K.-Y., Park, J.-B., Kim, C.-N., et al., 2006 : Field study of emission characteristics of ammonia and hydrogen sulfide by pig building types, J. Korean Soc. Occup. Environ. Hyg., 16, pp.36-43.

Kim, M-.S., Koo, N., Kim, J.-G., 2020 : A comparative study on ammonia emission inventory in livestock manure compost application through a foreign case study, Korean J. Environ. Biol., 38, pp.71-81. 10.11626/KJEB.2020.38.1.071

Cho, S.-B., Hwang, O.-H., Lee, G., et al., 2015 : The study on investigation of factors and reduction for odor generating substrates from hog farm, NIAS Grant(No. PJ008606), National Institute of Animal Science, Wanju, Korea.

Han, J., Park, S., Song, J.-H., et al., 2018 : A study to establish the 2nd integrated malodor prevention policy, NIER-SP2018-233, National Institute of Environmental Research, Incheon, Korea.

Wang, Y. C., Han, M. F., Jia, T. P., et al., 2021 : Emissions, measurement, and control of odor in livestock farms: A review, Sci. Total Environ., 776, 145735. 10.1016/j.scitotenv.2021.14573533640544

Poling, B. E., Prausnitz, J. M., O'Connell, J. P., 2001 : The properties of gases and liquids: McGraw-Hill Education, New York.

Cheema, I. I., Krewer, U., 2018 : Operating envelope of Haber-Bosch process design for power-to-ammonia, RSC Adv., 8(61), pp.34926-34936. 10.1039/C8RA06821F35547069PMC9087324

Susaya, J., Kim, K., 2010 : Removal of gaseous NH3 by water as a sorptive medium: the role of water volume and absorption time, Fresenius Environ. Bull., 19(4a), pp.745-750.

Hanson, D., Kosciuch, E., 2003 : The NH₃ mass accommodation coefficient for uptake onto sulfuric acid colutions, J. Phys. Chem. A, 107(13), pp.2199-2208. 10.1021/jp021570j

Lee, J. W., Barin, G., Peterson, G. W., et al., 2017 : A microporous amic acid polymer for enhanced ammonia capture, ACS Appl. Mater. Interfaces 9(39), pp.33504-33510. 10.1021/acsami.7b0260328388032

Moribe, S., Chen, Z., Alayoglu, S., et al., 2019 : Ammonia capture within isoreticular metal-organic frameworks with rod secondary building units, ACS Mater. Lett., 1(4), pp.476-480. 10.1021/acsmaterialslett.9b00307

Nijem, N., Fursich, K., Bluhrn, H., et al., 2015 : Ammonia adsorption and co-adsorption with water in HKUST-1: Spectroscopic evidence for cooperative interactions, J. Phys. Chem. C, 119(44), pp.24781-24788. 10.1021/acs.jpcc.5b05716

Bandosz, T. J., 2006 : Activated carbon surfaces in environmental remediation. Elsevier. New York.

Mochizuki, T., Kubota, M., Matsuda, H., et al., 2016 : Adsorption behaviors of ammonia and hydrogen sulfide on activated carbon prepared from petroleum coke by KOH chemical activation, Fuel Process. Technol, 144, pp.164-169. 10.1016/j.fuproc.2015.12.012

Zhang, F., Liang, M., Ye, C., et al., 2020 : Removal of ammonia and hydrogen sulfide from livestock farm by copper modified activated carbon, Global Nest J., 22(2), pp.165-172.

Qajar, A., Peer, M., Andalibi, M. R., et al., 2015 : Enhanced ammonia adsorption on functionalized nanoporous carbons, Microporous Mesoporous Mat., 218, pp.15-23. 10.1016/j.micromeso.2015.06.030

Matito-Martos, I., Martin-Calvo, A., Ania, C. O., et al., 2020 : Calero, S. Role of hydrogen bonding in the capture and storage of ammonia in zeolites, Chem. Eng. J., 387, 124062. 10.1016/j.cej.2020.124062

Lucero, J. M., Crawford, J. M., Wolden, C. A., et al., 2021 : Tunability of ammonia adsorption over NaP zeolite, Microporous Mesoporous Mater, 324, 111288. 10.1016/j.micromeso.2021.111288

Seredych, M., Ania, C., Bandosz, T. J., 2016 : Moisture insensitive adsorption of ammonia on resorcinol-formaldehyde resins, J. Hazard. Mater., 305, pp.96-104. 10.1016/j.jhazmat.2015.11.02226651066

Helminen, J., Helenius, J., Paatero, E., et al., 2000 : Comparison of Sorbents and Isotherm Models for NH₃-Gas Separation by Adsorption, AIChE J., 46(8), pp.1541-1555 10.1002/aic.690460807

Cao, Z., Akhtar, F., 2021 : Porous strontium chloride scaffolded by graphene networks as ammonia carriers, Adv. Funct. Mater., 31(30), 2008505. 10.1002/adfm.202008505

Tian, X., Qiu, J., Wang, Z., et al., 2022 : A record ammonia adsorption by calcium chloride confined in covalent organic frameworks, ChemComm, 58(8), pp.1151-1154. 10.1039/D1CC06308A34981086

Zhao, X., Wang, Y. X., Li, D. S., et al., 2018 : Metal-organic frameworks for separation, Adv. Mater., 30(37), 1705189. 10.1002/adma.20170518929582482

Vikrant, K., Kumar, V., Kim, K.H., et al., 2017 : Metal-organic frameworks (MOFs): potential and challenges for capture and abatement of ammonia, J. Mater. Chem. A, 5(44), pp.22877-22896. 10.1039/C7TA07847A

Rieth, A. J., Dinca, M., 2018 : Controlled gas uptake in metal-organic frameworks with record ammonia sorption, J. Am. Chem. Soc., 140(9), pp.3461-3466. 10.1021/jacs.8b0031329425040

Kim, D.-W., Kang, D.-W., Kang, M., et al., 2020 : High ammonia uptake of a metal-organic framework adsorbent in a wide pressure range, Angew. Chem, Int. Ed., 59(50), pp.22531-22536. 10.1002/anie.20201255232969148

Vikrant, K., Kumar, V., Kim, K. H., et al., 2017 : Metal-organic frameworks (MOFs): potential and challenges for capture and abatement of ammonia, J. Mater. Chem. A, 5(44), pp.22877-22896 10.1039/C7TA07847A

Rieth, A. J., Wright, A. M., Dinca, M., 2019 : Kinetic stability of metal-organic frameworks for corrosive and coordinating gas capture, Nat. Rev. Mater., 4(11), pp.708-725. 10.1038/s41578-019-0140-1

Jasuja, H., Peterson, G. W., Decoste, J. B., et al., 2015 : Evaluation of MOFs for air purification and air quality control applications: Ammonia removal from air, Chem. Eng. Sci., 124, pp.118-124. 10.1016/j.ces.2014.08.050

Yang, Y., Faheem, M., Wang, L., et al., 2018 : Surface pore engineering of covalent organic frameworks for ammonia capture through synergistic multivariate and open metal site approaches, ACS Cent. Sci., 4(6), pp.748-754. 10.1021/acscentsci.8b0023229974070PMC6026774

Luo, L., Li, J., Chen, X., et al., 2022 : Superhigh and reversible NH₃ uptake of cobaltous thiocyanate functionalized porous poly ionic liquids through competitive and cooperative interactions, Chem. Eng. J., 427, 131638. 10.1016/j.cej.2021.131638

Yang, H., Zuttel, A., Kim, S., et al., 2017 : Effect of boron doping on graphene oxide for ammonia adsorption, ChemNanoMat, 3(11), pp.794-797. 10.1002/cnma.201700187

Yang, C., Wang, J. F., Chen, Y., et al., 2018 : One-step template-free synthesis of 3D functionalized flower-like boron nitride nanosheets for NH₃ and CO₂ adsorption, Nanoscale, 10(23), pp.10979-10985. 10.1039/C8NR02074D29856461

Takahashi, A., Tanaka, H., Parajuli, D., et al., 2016 : Historical pigment exhibiting ammonia gas capture beyond standard adsorbents with adsorption sites of two kinds, J. Am. Chem. Soc., 138(20), pp.6376-6379. 10.1021/jacs.6b0272127147127

Szymula, A., Wlazło, Ł., Sasáková, N., et al., 2021 : The Use of Natural Sorbents to Reduce Ammonia Emissions from Cattle Faeces, Agronomy. 11(12), 2543. 10.3390/agronomy11122543

Information

Publisher :The Korean Institute of Resources Recycling
Publisher(Ko) :한국자원리싸이클링학회
Journal Title :Resources Recycling
Journal Title(Ko) :자원리싸이클링
Volume : 32
No :6
Pages :45-53
Received Date : 2023-12-11
Revised Date : 2023-12-20
Accepted Date : 2023-12-21
DOI :https://doi.org/10.7844/kirr.2023.32.6.45

Resources Recycling ISSN:2765-3439(Print) 2765-3447(Online) 자원리싸이클링

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